{"id":82,"date":"2019-01-21T10:28:12","date_gmt":"2019-01-21T01:28:12","guid":{"rendered":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/?p=82"},"modified":"2019-01-22T10:38:12","modified_gmt":"2019-01-22T01:38:12","slug":"%e8%ab%96%e6%96%87-%e5%a1%a9%e9%85%b8%e6%ba%b6%e5%aa%92%e4%b8%ad%e3%81%ae%e9%8a%85ii%e3%82%af%e3%83%ad%e3%83%ad%e9%8c%af%e4%bd%93%e5%88%86%e5%b8%83%e3%81%a8%e6%a7%8b%e9%80%a0%e3%81%ae%e6%b1%ba","status":"publish","type":"post","link":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/news\/82\/","title":{"rendered":"[\u8ad6\u6587] \u5869\u9178\u6eb6\u5a92\u4e2d\u306e\u9285(II)\u30af\u30ed\u30ed\u932f\u4f53\u5206\u5e03\u3068\u69cb\u9020\u306e\u6c7a\u5b9a"},"content":{"rendered":"<table>\n<tbody>\n<tr>\n<td><a href=\"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-content\/uploads\/sites\/98\/Fig07.png\"><img loading=\"lazy\" decoding=\"async\" class=\"size-medium wp-image-86 aligncenter\" src=\"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-content\/uploads\/sites\/98\/Fig07-300x219.png\" alt=\"Fig07\" width=\"300\" height=\"219\" srcset=\"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-content\/uploads\/sites\/98\/Fig07-300x219.png 300w, https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-content\/uploads\/sites\/98\/Fig07.png 444w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p>\u9285(II)\u30af\u30ed\u30ed\u932f\u4f53\u306e\u69cb\u9020<\/td>\n<td style=\"text-align: left;vertical-align: top\">\u00a0\u6eb6\u5a92\u62bd\u51fa\u6cd5\u30fb\u30a4\u30aa\u30f3\u4ea4\u63db\u6cd5\u306f\u3001\u91d1\u5c5e\u306e\u5206\u96e2\u30fb\u7cbe\u88fd\u306e\u307f\u306a\u3089\u305a\u3001\u6c34\u306e\u7cbe\u88fd\u3001\u5de5\u5834\u6392\u6c34\u306e\u51e6\u7406\u306a\u3069\u591a\u304f\u306e\u7528\u9014\u3067\u4f7f\u7528\u3055\u308c\u3066\u3044\u308b\u3002\u8fd1\u5e74\u306f\u3001\u7279\u5b9a\u306e\u30a4\u30aa\u30f3\u306e\u9078\u629e\u6027\u3092\u9ad8\u3081\u305f\u5438\u7740\u5264\u30fb\u5b98\u80fd\u57fa\u306e\u958b\u767a\u304c\u76db\u3093\u3067\u3042\u308b\u3002\u5438\u7740\u53cd\u5fdc\u30fb\u4ea4\u63db\u53cd\u5fdc\u306f\u3001\u5b98\u80fd\u57fa\u306e\u7279\u6027\u306b\u4f9d\u5b58\u3059\u308b\u3068\u5171\u306b\u3001\u5438\u7740\u524d\u306e\u6c34\u6eb6\u6db2\u4e2d\u3067\u306e\u30a4\u30aa\u30f3\u306e\u5206\u5e03\u306b\u3082\u5f37\u304f\u4f9d\u5b58\u3059\u308b\u3002\u3057\u304b\u3057\u306a\u304c\u3089\u3001\u71b1\u529b\u5b66\u7684\u89e3\u6790\u306f\u3044\u307e\u3060\u5145\u5206\u3067\u306f\u306a\u3044\u3002\u305d\u3053\u3067\u3001\u672c\u8ad6\u6587\u3067\u306f\u3001\u5869\u9178\u6eb6\u5a92\u4e2d\u306b\u304a\u3051\u308b\u9670\u30a4\u30aa\u30f3\u4ea4\u63db\u53cd\u5fdc\u306e\u71b1\u529b\u5b66\u7684\u89e3\u6790\u306b\u5fc5\u8981\u4e0d\u53ef\u6b20\u306a\u3001\u9285(II)\u30af\u30ed\u30ed\u932f\u4f53\u306e\u5206\u5e03\u3068\u69cb\u9020\u3092\u3001\u7d2b\u5916\u53ef\u8996\u5438\u53ce\u30b9\u30da\u30af\u30c8\u30eb\u3068X\u7dda\u5438\u53ce\u30b9\u30da\u30af\u30c8\u30eb\u3092\u4e3b\u6210\u5206\u5206\u6790\u3068\u71b1\u529b\u5b66\u30e2\u30c7\u30eb\u306e\u30d5\u30a3\u30c3\u30c6\u30a3\u30f3\u30b0\u89e3\u6790\u3001\u304a\u3088\u3073X\u7dda\u5438\u53ce\u5fae\u7d30\u69cb\u9020\u30b9\u30da\u30af\u30c8\u30eb\u306e\u89e3\u6790\u306b\u3088\u308a\u6c7a\u5b9a\u3057\u305f\u3002\u9285(II)\u30af\u30ed\u30ed\u932f\u4f53\u306f\u3001[Cu<sup>II<\/sup>(H<sub>2<\/sub>O)<sub>6<\/sub>]<sup>2+<\/sup>\u3001[Cu<sup>II<\/sup>(H<sub>2<\/sub>O)<sub>5<\/sub>Cl]<sup>+<\/sup>\u3001[Cu<sup>II<\/sup>Cl<sub>2<\/sub>(H<sub>2<\/sub>O)<sub>4<\/sub>]<sup>0<\/sup>\u3001[Cu<sup>II<\/sup>Cl<sub>3<\/sub>]<sup>\u2212<\/sup>\u3001[Cu<sup>II<\/sup>Cl<sub>4<\/sub>]<sup>2\u2212<\/sup>\u306e5\u7a2e\u985e\u304c\u5b58\u5728\u3059\u308b\u3053\u3068\u304c\u78ba\u8a8d\u3055\u308c\u305f\u3002\u3055\u3089\u306b\u3001[Cu<sup>II<\/sup>(H<sub>2<\/sub>O)<sub>6<\/sub>]<sup>2+<\/sup>\u3001[Cu<sup>II<\/sup>(H<sub>2<\/sub>O)<sub>5<\/sub>Cl]<sup>+<\/sup>\u3001[Cu<sup>II<\/sup>Cl<sub>2<\/sub>(H<sub>2<\/sub>O)<sub>4<\/sub>]<sup>0<\/sup>\u306e\u69cb\u9020\u3092\u8ef8\u65b9\u5411\u306b\u4f38\u3073\u305f\u516b\u9762\u4f53\u69cb\u9020\u3001[Cu<sup>II<\/sup>Cl<sub>3<\/sub>]<sup>\u2212<\/sup>\u306f\u5e73\u9762\u4e09\u89d2\u5f62\u69cb\u9020\u3001[Cu<sup>II<\/sup>Cl<sub>4<\/sub>]<sup>2\u2212<\/sup>\u306e\u304c\u6b63\u56db\u9762\u4f53\u69cb\u9020\u3067\u3042\u308b\u3053\u3068\u3092\u6c7a\u5b9a\u3057\u305f\u3002<\/p>\n<p>\u4eca\u5f8c\u306e\u6eb6\u5a92\u62bd\u51fa\u6cd5\u30fb\u30a4\u30aa\u30f3\u4ea4\u63db\u6cd5\u306e\u89e3\u6790\u306b\u671f\u5f85\u3055\u308c\u308b\u3002<\/p>\n<p>Uchikoshi, M and Shinoda K:\u00a0Determination of structures of cupric-chloro complexes in hydrochloric acid solutions by UV-Vis and X-ray absorption spectroscopy, <em>Struct. Chem.<\/em>, <strong>30<\/strong>(1), 61\u201374 (2019).\u00a0<a href=\"https:\/\/doi.org\/10.1007\/s11224-018-1164-7\" target=\"_blank\">https:\/\/doi.org\/10.1007\/s11224-018-1164-7<\/a><\/p>\n<p><a href=\"http:\/\/rdcu.be\/qduW\" target=\"_blank\">http:\/\/rdcu.be\/qduW<\/a>\u00a0\u2190\u3053\u306e\u30ea\u30f3\u30af\u304b\u3089\u3082\u8ad6\u6587\u3092\u8aad\u3080\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u305f\u3060\u3057\u3001\u30c0\u30a6\u30f3\u30ed\u30fc\u30c9\u3001\u5370\u5237\u306f\u3067\u304d\u307e\u305b\u3093\u3002<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u9285(II)\u30af\u30ed\u30ed\u932f\u4f53\u306e\u69cb\u9020 \u00a0\u6eb6\u5a92\u62bd\u51fa\u6cd5\u30fb\u30a4\u30aa\u30f3\u4ea4\u63db\u6cd5\u306f\u3001\u91d1\u5c5e\u306e\u5206\u96e2\u30fb\u7cbe\u88fd\u306e\u307f\u306a\u3089\u305a\u3001\u6c34\u306e\u7cbe\u88fd\u3001\u5de5\u5834\u6392\u6c34\u306e\u51e6\u7406\u306a\u3069\u591a\u304f\u306e\u7528\u9014&#8230;<\/p>\n","protected":false},"author":70,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"class_list":["post-82","post","type-post","status-publish","format-standard","hentry"],"_links":{"self":[{"href":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-json\/wp\/v2\/posts\/82","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-json\/wp\/v2\/users\/70"}],"replies":[{"embeddable":true,"href":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-json\/wp\/v2\/comments?post=82"}],"version-history":[{"count":8,"href":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-json\/wp\/v2\/posts\/82\/revisions"}],"predecessor-version":[{"id":91,"href":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-json\/wp\/v2\/posts\/82\/revisions\/91"}],"wp:attachment":[{"href":"https:\/\/www2.tagen.tohoku.ac.jp\/lab\/nonferrous\/wp-json\/wp\/v2\/media?parent=82"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}