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Last update September 9, 2022


最近の成果です。This is our recent achievement.

これまでの成果はResearch Map(柴田先生助永先生川西先生)よりご覧ください。



Original Research Paper

  • Sohei Sukenaga, Hiroki Unozawa, Yuki Chiba, Masanori Tashiro, Sakiko Kawanishi, and Hiroyuki Shibata: “Incorporation limit of MoO3 in sodium borosilicate glasses”, Journal of the American Ceramic Society, in Press.
  • 篠田弘造, 助永壮平: “高清浄度クロム鋼溶製を目的とするスラグ制御のための溶存金属酸化物の化学状態分析”, 鉄と鋼, 108(8) (2022), pp.455-460.
  • Issei Suzuki, Sakiko Kawanishi, Takahisa Omata, Hiroshi Yanagi: “Current status of n-type SnS: paving the way for SnS homojunction solar cells”, Journal of Physics: Energy, in press.
    DOI: 10.1088/2515-7655/ac86a1
  • Issei Suzuki, Sakiko Kawanishi, Kiyohisa Tanaka, Takahisa Omata, Shin-ichiro Tanaka: “Contribution of the Sn 5s state to the SnS valence band: direct observation via ARPES measurements”, Electronic Structure, 4 (2022), 025004 (7 pages).
    DOI: 10.1088/2516-1075/ac6ea8
  • Kyung-Ho Kim, Sohei Sukenaga, Masanori Tashiro, Koji Kanehashi, Shinichiro Yoshida, and Hiroyuki Shibata: “Variation in viscosity of aluminosilicate melts with MgO/CaO molar ratio: influence of five-fold coordinated aluminum”, Journal of Non-Crystalline Solids, 587 (2022), 121600 (5 pages).
  • Kenji Shinozaki, Yoshiki Ishii, Sohei Sukenaga, and Koji Ohara: “Ultrafast Nanocrystallization of BaF2 in Oxyfluoride Glasses with Crystal-like Nanostructures: Implications for Upconversion Fiber Devices”, ACS Applied Nano Materials, (2022), 5(3) (2022),4281-4292.
  • Raquel Simancas, Masamori Takemura, Yasuo Yonezawa, Sohei Sukenaga, Mariko Ando, Hiroyuki Shibata, Anand Chokkslingm, Kenta Iyoki, Tatsuya Ohkubo, and Toru Wakihara: “Exploring Hydrothermal Synthesis of SAPO-18 under High Hydrostatic Pressure”, Nanomaterials, 12(3) (2022), 396 (12 pages).
  • Sakiko Kawanishi, Hiroyuki Shibata, and Takeshi Yoshikawa: “Contribution of Dislocations in SiC Seed Crystals on the Melt-Back Process in SiC Solution Growth”, Materials, 15(5) (2022), 1796 (8 pages).
    DOI: 10.3390/ma15051796
  • Issei Suzuki, Sakiko Kawanishi, Naoki Ohashi, Aiga Gomi, Junya Kano, Hiroto Watanabe, Satoshi Asano, Takahisa Omata: “First Principles Calculation of Electrical and Optical Properties of Cu3AsO4: Promising Thin-Film Solar Cell Absorber from Nonferrous Metal Manufacturing By-Products”, Materials Transactions, 63(1) (2022), 73-81.
    DOI: 10.2320/matertrans.M-M2021851
  • Kenta Iyoki, Takeko Onishi, Mariko Ando, Sohei Sukenaga, Hiroyuki Shibata, Tatsuya Okubo and Toru Wakihara: “reduction of crystal size of silicate-1 synthesized in fluoride-containing media via multi-stage heating with intermediate stirring”, Journal of the Ceramic Society of Japan, 130 (1) (2022), pp.187-194.
  • Issei Suzuki, Zexin Lin, Sakiko Kawanishi, Kiyohisa Tanaka, Yoshitaro Nose, Takahisa Omata, Shin-ichiro Tanaka: “Direct evaluation of hole effective mass of SnS–SnSe solid solutions with ARPES measurement”, Physical Chemistry Chemical Physics, 24 (2022), 634.
    DOI: 10.1039/D1CP04553A

Reprinted Article

  • 助永壮平,小川将幸,簗場豊,安東真理子,柴田浩幸: “Na–Si–O–N–F系融体の粘度: 酸素,窒素およびフッ素の混合効果”, 鉄と鋼, 108 (3) (2022), in press.


  • 助永壮平: “ケイ酸塩系複合アニオン融体の粘度”, ふぇらむ(日本鉄鋼協会会報), 27 (4) (2022), 210-213.



Original Research Paper

  • Issei Suzuki, Sakiko Kawanishi, Sage R. Bauers, Andriy Zakutayev, Hiroyuki Shibata, Hiroshi Yanagi, and Takahisa Omata: “N-Type Electrical Conduction in SnS Thin films”, Physical Review Materials, 5 (2021), 125405 (8 pages).
    DOI: 10.1103/PhysRevMaterials.5.125405
  • Ruan Fang, Sakiko Kawanishi, Sohei Sukenaga and Hiroyuki Shibata: “Inhibitory Effect of MgO, FeO, CaF2, and Al2O3 Additives on the Elution Behavior of Ca from Silicate Mineral Phases into Water”, Metallurgical and Materials Transactions B, advanced online publication.
    DOI: 10.1007/s11663-021-02376-3
  • Sohei Sukenaga, Takahiko Endo, Tsuyoshi Nishi, Hiroki Yamada, Koji Ohara, Toru Wakihara, Koji Inoue, Sakiko Kawanishi, Hiromichi Ohta, and Hiroyuki Shibata: “Thermal Conductivity of Sodium Silicate Glasses and Melts: Contribution of Diffusive and Propagative Vibration Modes”, Frontiers in Materials, 8 (2021), 753746 (9 pages).
    DOI: 10.3389/fmats.2021.753746
  • Sakiko Kawanishi, Hironori Daikoku, Hiroyuki Shibata, and Takeshi Yoshikawa: “Suppressing solvent compositional change during solution growth of SiC using SiC/C gradient crucible”, Journal of Crystal Growth, 576 (2021), 126382 (8 pages).
    DOI: 10.1016/j.jcrysgro.2021.126382
  • Wei Wang, Yong Wang, Wangzhong Mu, Joo Hyun Park, Hui Kong, Sohei Sukenaga, Hiroyuki Shibata, Henrik Larsson, and Huahai Mao: “Inclusion Engineering in Co-based Duplex Entropy Alloys”, Materials & Design, 210 (2021), 110097 (12 pages).
    DOI: 10.1016/j.matdes.2021.110097
  • Seunghwan Shin, Sakiko Kawanishi, Sohei Sukenaga, Makoto Ohtsuka, Junichi Takahashi and Hiroyuki Shibata: “Elucidation of gas formation effect on strong inhibition of magnetite dissolution in Cu2S through in-situ analysis of reactive interface”, Metallurgical and Materials Transactions B,  52 (2021), pp. 3720–3729.
    DOI: 10.1007/s11663-021-02279-3
  • Nobuo Nishioka, Yui Hosono, Sohei Sukenaga, Noritaka Saito and Kunihiko Nakashima: “Effect of Glass Composition on Sinterability of Copper Terminal Paste for Multilayer Ceramic Capacitor”, Materials Transactions, 62(10) (2021), pp.1583-1588.
    DOI: 10.2320/matertrans.MT-M2021067
  • Sakiko Kawanishi, Shogo Hachinoda, and Hiroyuki Shibata: “Negligible Temperature Dependence of Nitrogen Solubility in Molten Silicon-Chromium Alloys at Middle Composition Range”, Materials Transactions, 62(10) (2021), pp. 1519-1523.
    DOI: 10.2320/matertrans.MT-M2021074
  • Masanori Tashiro, Sohei Sukenaga, Koichi Ikemoto, Kozo Shinoda, Tsuyoshi Kajitani, Shigeru Suzuki, and Hiroyuki Shibata: “Interfacial Reactions between Pure Cu, Ni, and NiーCu Alloys and p-type Bi2Te3 Bulk Thermoelectric Material”, Journal of Materials Science, 56(29) (2021), pp.16545-16557.
    DOI: 10.1007/s10853-021-06358-3
  • Ching-Tien Chen, Kenta Iyoki, Peidong Hu, Hiroki Yamada, Koji Ohara, Sohei Sukenaga, Mariko Ando, Hiroyuki Shibata, Tatsuya Okubo, and Toru Wakihara, “Reaction Kinetics Regulated Formation of Short-Range Order in an Amorphous Matrix during Zeolite Crystallization”, Journal of the American Chemical Society, 143(29) (2021), 10986-10997.
    DOI: 10.1007/s10853-021-06358-3
  • Sohei Sukenaga, Koji Ohara, Hiroki Yamada, Toru Wakihara, and Hiroyuki Shibata, “Reconsideration of viscosity variation mechanism in calcium ferrite melt during isothermal melting process”, Metallurgical and Materials Transactions B, 52(4)(2021),1945-1949.
    DOI: 10.1007/s11663-021-02227-1
  • Masanori Tashiro, Sohei Sukenaga, Koichi Ikemoto, Kozo Shinoda, Tsuyoshi Kajitani, Shigeru Suzuki, and Hiroyuki Shibata: “Investigation of Interfacial Reactions between Metallic Substrates and n-type Bulk Bismuth Telluride Thermoelectric Material”, Journal of Materials Science, 56(25)(2021),14170-14180.
    DOI: 10.1007/s10853-021-06198-1
  • Shohei Koizumi, Xu Gao, Sohei Sukenaga, Koji Kanehashi, Takafumi Takahashi, Shigeru Ueda, and Shin-ya Kitamura: “Influence of Glass Structure on the Dissolution Behavior of Fe from Glassy Slag of CaO-SiO2-FeOx System”, Journal of Sustainable Metallurgy, 7(2)(2021),583-596.
  • Sakiko Kawanishi, Takeshi Yoshikawa, Didier Chaussende, and Hiroyuki Shibata: “In situ interferometry for ppm-order solubility analysis at high temperatures: A case study of carbon solubility in molten silicon”, Metallurgical and Materials Transactions B, 52(4)(2021),2619-2625.
    DOI: 10.1007/s11663-021-02216-4
  • Mattia De Colle, Sohei Sukenaga, Ko Mibu, Yusuke Kato, Hisahiro Matsunaga, Pär Jönsson, Andrey Karasev, and Hiroyuki Shibata: “Study of the Hydration Behavior of Synthetic Ferropericlase with Low Iron Oxide Concentrations to Prevent Swelling in Steel Slags”, Journal of Sustainable Metallurgy, 7(2)(2021),547-558.
    DOI: 10.1007/s40831-021-00359-x
  • Hironori Daikoku, Sakiko Kawanishi, Takehiko Ishikawa and Takeshi Yoshikawa: “Density, surface tension, and viscosity of liquid Si–Cr alloys and influence on temperature and fluid flow during solution growth of SiC”, The Journal of Chemical Thermodynamics, 160 (2021), 106476 (7 pages).
    DOI: 10.1016/j.jct.2021.106476
  • Sakiko Kawanishi, Issei Suzuki, Sage R. Bauers, Andriy Zakutayev, Hiroyuki Shibata, Hiroshi Yanagi, and Takahisa Omata: “SnS Homojunction Solar Cell with n-type Single Crystal and p-type Thin Film”, Solar RRL, 5(4) (2021), 2000708 (7 pages).
    DOI: 10.1002/solr.202000708
  • Ruan Fang, Sakiko Kawanishi, Sohei Sukenaga and Hiroyuki Shibata: “Effect of the Silicate Skeleton Structure on the Dissolution Kinetics of Calcium Silicate Mineral Phases in Water”, Metallurgical and Materials Transactions B, 52(2) (2021), 1071-1084.
    DOI: 10.1007/s11663-021-02079-9


  • 柴田浩幸, 坂本満, 熊谷枝折: “循環社会におけるマグネシウムの新しい役割-マグネシウム合金をエネルギーキャリアにしてはどうか-”, 金属, 91(12) (2021), 1021-1027.


  • 佐藤修彰, 柴田浩幸, 柴田悦郎: 乾式プロセス, 内田老鶴圃, (2021)

Book Chapter

  • Sohei Sukenaga and Hiroyuki Shibata: “High-Temperature Characterization of Glasses and Melts”, Encyclopedia of Materials: Technical Ceramics and Glasses (edited by M. Pomeroy), Vol.1 (2021), pp.689-703, Elsevier
    DOI: 10.1016/B978-0-12-818542-1.00024-2
  • 助永壮平: 分担執筆3節 製鋼工程 (D. 二次精錬 & E.連続鋳造), 乾式プロセス (佐藤修彰, 柴田浩幸, 柴田悦郎編), 内田老鶴圃, (2021), pp.89-98.
  • 助永壮平: 分担執筆4節 放射性廃棄物処理 (B.ガラス固化プロセス), 乾式プロセス (佐藤修彰、柴田浩幸、柴田悦郎編), 内田老鶴圃, (2021), pp.244-259.



Original Research Paper

  • Sohei Sukenaga, Masayuki Ogawa, Yutaka Yanaba, Mariko Ando, Hiroyuki Shibata: “Viscosity of Na–Si–O–N–F Melts: Mixing Effect of Oxygen, Nitrogen, and Fluorine”, ISIJ International, 60(12), (2020), 2794-2806.
    DOI: 10.2355/isijinternational.ISIJINT-2020-326
  • Ko-ichiro Ohno, Shungo Natsui, Sohei Sukenaga, Kazui Tonya, Takayuki Maeda, Kazuya Kunitomo: “Numerical Approach to Comprehend for Effect of Melts Physical Properties on Iron-slag Separation Behaviour of Self-reducing Pellet”, ISIJ International, 60(12), (2020), 2695-2704.
    DOI: 10.2355/isijinternational.isijint-2020-218
  • Kenji Shinozaki, Sohei Sukenaga, koji Ohara: “Photoluminescence and structural similarity of crystals with oxidefluoride stacking structure and oxyfluoride glass”, Journal of the Ceramic Society of Japan, 128(12), (2020), 1030-1037.
    DOI: 10.2109/jcersj2.20168
  • Wei Wang, Wangzhong Mu, Ziyong Hou, Sohei Sukenaga, Hiroyuki Shibata, Henrik Larsson, Huahai Mao: “In-situ real time observation of martensite transformation in duplex fcc+hcp cobalt based entropic alloys”, Materialia, 14(12), (2020), 100928.
    DOI: 10.1016/j.mtla.2020.100928
  • Sakiko Kawanishi, Yoichiro Nagamatsu, Takeshi Yoshikawa and Hiroyuki Shibata:
    “Availability of Cr-rich Cr-Si solvent for rapid solution growth of 4H-SiC”, Journal of Crystal
    Growth, 549 (2020), 125877.
    DOI: 10.1016/j.jcrysgro.2020.125877
  • Sakiko Kawanishi, Issei Suzuki, Takeo Ohsawa, Naoki Ohashi, Hiroyuki Shibata and
    Takahisa Omata: “Growth of large single crystals of n-type SnS from halogen-added Sn
    flux”, Crystal Growth and Design, 20(9) (2020), 5931-5939.
    DOI: 10.1021/acs.cgd.0c00617
  • Sakiko Kawanishi, Ryo Watanabe and Hiroyuki Shibata: “Nucleation control of 3C-SiC induced by spiral structure of 6H-SiC”, Crystal Growth and Design, 20(7) (2020), 4740-4748.
  • Shinsuke Ogyu, Lichun Zheng, Xu Gao, Shigeru Ueda, Sohei Sukenaga, Shin-ya Kitamura:
    ”Influence of gasification reaction of coke on sliding and dynamic contact angles of droplets
    in a blast furnace”, ISIJ International 60(7) (2020), 1401-1408.
  • Ko-ichiro Ohno, Yoshiki Kitamura, Sohei Sukenaga, Shungo Natsui, Takayuki Maeda, Kazuya Kunitomo: “Gas permeability evaluation of granulated slag particles packed bed during softening and melting stage with Fanning’s equation”, ISIJ International 60(7) (2020),
  • Tatsuya Yoshioka, Zhendon Liu, Kenta Iyoki, Tsuneji Sano, Mariko Ando, Sohei Sukenaga,
    Hiroyuki Shibata, Tatsuya Okubo, and Toru Wakihara: “Rapid synthesis of hydrothermally
    stable ZSM-5 in the presence of 1-Butanol”, Chemistry Letters 49(9) (2020), 1006-1008.
  • Masanori Tashiro, Sohei Sukenaga, Sakiko Kawanishi, Yohei Sato, Yuji Takakuwa, Hiroyuki Shibata: “Experimental determination of solidified lithium disilicate crystal bandgap energy using EELS and XPS”, Journal of the American Ceramics Society, 103(9) (2020), 5139-5144.
  • Sakiko Kawanishi, Mai Abe, Chihiro Koyama, Takehiko Ishikawa and Hiroyuki Shibata: “Measurement of thermophysical properties of molten Si-Cr and Si-Fe alloys for design of solution growth of SiC”, Journal of Crystal Growth, 541(2020), 125658.
  • Sakiko Kawanishi and Takeshi Yoshikawa: “Measurement and thermodynamics of the carbon solubilities in molten Si–Fe, Si–Ni, and Si–Cr–Fe alloys at 2073 K”, ISIJ International, 60 (10) (2020), advance online publication.
  • Ruan Fang, Sakiko Kawanishi, Sohei Sukenaga and Hiroyuki Shibata: “Effect of the silicate structure on calcium elution behaviors of calcium-silicate based mineral phases in aqueous solution”, ISIJ International, 60 (3) (2020), 419-425.
  • Shungo Natsui, Kazui Tonya, Hiroshi Nogami, Tatsuya Kikuchi, Rysuke O. Suzuki, Ko-ichiro Ohno, Sohei Sukenaga, Tatsuya Kon, Shingo Ishihara, Shigeru Ueda: “Numerical study of binary trickle flow of liquid iron and molten slag in coke bed by smoothed particle hydrodynamics”, Processes, 8(2) (2020), 221.
  • Che Tan, Zhendong Liu, Yasuo Yonezawa, Sohei Sukenaga, Mariko Ando, Hiroyuki
    Shibata, Yukichi Sasaki, Tatsuya Okubo, and Toru Wakihara: “Unique crystallization
    behavior in zeolite synthesis under external high pressure”, Chemical Communications
    56(18) (2020), 2811-2814.
  • Xuan Changji, Nakajima Keiji, Shibata Hiroyuki, Jonsson Par Goran: “Wetting and spreading behavior of liquid iron on single crystal TiO2 substrate”, Materials Letters 258 (2020), 126778.
    DOI: 10.1016/j.matlet.2019.126778

Book Chapter

  • 柴田浩幸: 熱物性・熱分析ハンドブック 第3版(分担執筆),丸善出版,(2020)